Using critical fluid carbon dioxide to optimize the enzymatic transesterification of soybean oil and ethyl ferulate to feruloyl soy glycerides

نویسندگان

چکیده

Feruloyl Soy Glyceride (FSG) is an all-natural replacement for petroleum-based ultraviolet absorbing ingredients currently used in sunscreens. It produced by the Novozym® 435-catalyzed transesterification of ethyl ferulate (EF) with triglycerides. By-product fatty acid esters (FAEEs) are more soluble CO2 than EF and triglyceride starting materials. was hypothesized that preferential removal FAEEs over would drive enzymatic reaction towards desired FSG product. The effect pressure temperature on solubilities components mixture studied to select optimized conditions purification. Pressure–temperature were then selected use a recycling system. products analyzed without CO2. all proportional density but relative individual not equal at pressures temperatures. At 60°C, ratio linoleate only 1.1 6.9 MPa 3.1 13.8 MPa. recycled through reactor (removing FAEE by-products) receiver 6.0 less FAEEs). In treatment, material left behind had 99.6% content. reduced system effectively increased amount incorporated onto soybean oil increasing yield

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ژورنال

عنوان ژورنال: Journal of the American Oil Chemists' Society

سال: 2023

ISSN: ['0003-021X', '1558-9331']

DOI: https://doi.org/10.1002/aocs.12690